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3 article(s) from Schäberle, Till F.

Antibacterial scalarane from Doriprismatica stellata nudibranchs (Gastropoda, Nudibranchia), egg ribbons, and their dietary sponge Spongia cf. agaricina (Demospongiae, Dictyoceratida)

Cora Hertzer,
Stefan Kehraus,
Nils Böhringer,
Fontje Kaligis,
Robert Bara,
Dirk Erpenbeck,
Gert Wörheide,
Till F. Schäberle,
Heike Wägele and
Gabriele M. König

Beilstein J. Org. Chem. 2020, 16, 1596–1605, doi:10.3762/bjoc.16.132

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Graphical Abstract

Figure 1: Doriprismatica stellata nudibranch, egg ribbon, and Spongia cf. agaricina specimen.

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Figure 2: The structurally new 12-deacetoxy-4-demethyl-11,24-diacetoxy-3,4-methylenedeoxoscalarin (relative s...

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Figure 3: Superimposed HPLC–MS chromatogram of Doriprismatica stellata nudibranch, egg ribbon, and Spongia cf...

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Figure 4: Proposed relative configuration of 12-deacetoxy-4-demethyl-11,24-diacetoxy-3,4-methylenedeoxoscalar...

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Full Research Paper

Published 03 Jul 2020

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Marine-derived myxobacteria of the suborder Nannocystineae: An underexplored source of structurally intriguing and biologically active metabolites

Antonio Dávila-Céspedes,
Peter Hufendiek,
Max Crüsemann,
Till F. Schäberle and
Gabriele M. König

Beilstein J. Org. Chem. 2016, 12, 969–984, doi:10.3762/bjoc.12.96

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Figure 1: Structures of cystobactamids 507, 919-1 and 919-2.

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Figure 2: Structures of aurafuron A and corallopyronin A.

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Figure 3: Structures of ixabepilone and capecitabine.

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Figure 4: Structures of DKxanthene-534 and myxochelin A.

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Figure 5: Phylogenetic tree of halotolerant and halophilic myxobacteria. The neighbor-joining tree is based o...

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Figure 6: Structure of nannocystin A.

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Figure 7: Structure of phenylnannolones A–C.

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Figure 8: Structures of the pyrronazols, dihydroxyphenazin and 1-hydroxyphenazin-6-yl-α-D-arabinofuranoside.

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Figure 9: Structures of nannozinones A + B and nannochelin A from N. pusilla strain MNa10913.

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Figure 10: Structure of haliangicin from H. ochraceum.

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Figure 11: Structure of haliamide from H. ochraceum SMP-2.

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Figure 12: Structures of salimabromide, enhygrolides A + B and salimyxins A + B.

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Figure 13: Structures of miuraenamides A–F from P. miuraensis.

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Review

Published 13 May 2016

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Biosynthesis of α-pyrones

Till F. Schäberle

Beilstein J. Org. Chem. 2016, 12, 571–588, doi:10.3762/bjoc.12.56

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Figure 1: Selected monocyclic and monobenzo α-pyrone structures.

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Figure 2: The basic core structure of dibenzo-α-pyrones.

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Figure 3: Selected dibenzo-α-pyrones.

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Figure 4: Structure of ellagic acid and of the urolithins, the latter metabolized from ellagic acid by intest...

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Figure 5: Structure of murayalactone, the only dibenzo-α-pyrone described from bacteria.

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Figure 6: Structures of the 6-pentyl-2-pyrone (29) and of trichopyrone (30). Only 29 showed antifungal activi...

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Figure 7: Selected monocyclic α-pyrones.

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Figure 8: Structures of the gibepyrones A–F.

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Figure 9: Structures of the phomenins A and B.

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Figure 10: Structures of monocyclic α-pyrones showing pheromone (47) and antitumor activity (48), respectively....

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Figure 11: Structures of 6-alkyl (alkoxy or alkylthio)-4-aryl-3-(4-methanesulfonylphenyl)pyrones.

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Figure 12: Structures of kavalactones.

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Figure 13: Strutures of germicins.

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Figure 14: Structures of the pseudopyronines.

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Figure 15: The structures of the monobenzo-α-pyrone anticoagulant drugs warfarin and phenprocoumon.

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Figure 16: Structures of selected monobenzo-α-pyrones.

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Figure 17: Hypothetical pathway of 29 generation from linoleic acid [34].

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Figure 18: Proposed biosynthetic pathway of alternariol (modified from [77]). Malonyl-CoA building blocks are appl...

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Figure 19: Structures of phenylnannolones and of enterocin, both biosynthesized via polyketide synthase system...

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Figure 20: Pyrone ring formation. Examples for the three types of PKS systems are shown in A–C. In D the mecha...

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Figure 21: Structures of csypyrones.

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Figure 22: Schematic drawing of the T-shaped catalytic cavities of the related enzymes CorB and MxnB. The two ...

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Figure 23: Stereo representation of the CorB binding situation (modified from [89]). The substrate mimic (dark vio...

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Figure 24: Proposed mechanism for the CsyB enzymatic reaction. A) Coupling reaction of the β-keto fatty acyl i...

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Figure 25: Proposed biosynthesis of photopyrone D (37) by the enzyme PpyS from P. luminescens (modified from [63])...

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Review

Published 24 Mar 2016

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